%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3
scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                -0.80059981   -0.75360749    0.54273004
 C                  0.19590490    0.72082920    1.91670282
 C                 -0.22711368    1.52862959    1.09235043
 C                  1.57446649    2.63820438   -1.06483119
 H                  1.15011865    1.70636873   -1.44307852
 H                  1.93003838    3.19722120   -1.93611320
 C                  2.73179373    2.39055444   -0.13234538
 H                  3.20795232    3.29574271    0.23993905
 C                  3.25230902    1.22631460    0.29064243
 C                 -0.71291060    2.55032220    0.15952221
 H                 -1.45162111    3.16953090    0.67621342
 H                 -1.23004873    2.05343804   -0.66797890
 P                 -1.92532022   -2.51043940   -0.46624078
 C                 -3.69640752   -2.10300310   -0.70944114
 C                 -1.31370428   -3.03646276   -2.10832442
 H                  0.69176558    0.29105597    2.76507672
 H                  4.06777134    1.29792767    1.01058309
 C                  2.84550348   -0.15288748   -0.02620154
 C                  2.91729330   -1.12754165    0.98220747
 C                  2.40621359   -0.56869345   -1.29874921
 C                  2.52155398   -2.44884301    0.76675452
 H                  3.28228235   -0.84562110    1.96696674
 C                  2.01734214   -1.88209688   -1.53387156
 H                  2.41021478    0.13202562   -2.12678172
 C                  2.05851036   -2.82944800   -0.49922408
 H                  2.58930162   -3.16431354    1.57773334
 H                  1.70354640   -2.19954957   -2.52288914
 O                  1.63543587   -4.08725822   -0.82413243
 C                  1.86435109   -5.14245200    0.11054408
 H                  1.30017079   -4.99105890    1.03921085
 H                  1.51706136   -6.05347400   -0.37807755
 H                  2.93097407   -5.23261468    0.34730274
 C                 -1.90704914   -4.02752583    0.55981006
 H                 -2.34693378   -3.81680635    1.53812218
 H                 -2.47784779   -4.81859746    0.06287125
 H                 -0.87412942   -4.35497970    0.69456380
 H                 -4.14603288   -1.84067954    0.25183594
 H                 -4.22126093   -2.96300267   -1.13768065
 H                 -3.78277534   -1.24899604   -1.38695555
 H                 -1.24171584   -2.17304639   -2.77442977
 H                 -2.00844334   -3.76935765   -2.53204423
 H                 -0.32872782   -3.49270277   -1.99042080
 N                  0.40297113    3.46008153   -0.43500340
 S                 -0.50578325    4.90314322   -0.30915264
 O                 -1.15232149    5.28570542   -1.80063998
 O                 -1.74067737    4.68886940    0.79448826
 C                  0.55362131    6.22590374    0.23524298
 H                 -0.04355408    7.06641834    0.52127927
 H                  1.13208491    5.89761354    1.07339894
 H                  1.20916593    6.50882156   -0.56170041

C H N P S O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



