%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                  0.52200174   -2.98915722    1.16763443
 C                 -0.11569111   -2.32100036    0.38976160
 C                 -0.07303568    0.82431669    0.06323379
 H                  0.61130461    0.75260479   -0.78395721
 H                 -0.47266885    1.84526423    0.04978770
 C                  0.63952696    0.63968522    1.37586510
 H                  0.00785959    0.74117461    2.25785971
 C                  1.95995954    0.50787033    1.58247434
 C                 -0.87797767   -1.56956835   -0.60615525
 H                 -1.79479772   -2.11946495   -0.84196301
 H                 -0.29617841   -1.50661421   -1.53499279
 C                 -1.27893946   -0.11796692   -0.20624856
 O                 -3.25724579   -0.14904905   -1.52750921
 O                 -2.56364488    1.09328507    1.37041781
 C                 -4.07504922    0.28318728   -2.63673326
 H                 -3.56104748    0.08970967   -3.58135724
 H                 -4.99028010   -0.30331635   -2.56778542
 H                 -4.29134451    1.35082187   -2.55094498
 C                 -3.49443053    1.19415893    2.46876400
 H                 -4.44293047    0.72040207    2.20345930
 H                 -3.08289093    0.71115658    3.35846580
 H                 -3.63013336    2.26172309    2.63782731
 H                  1.08931266   -3.55380095    1.87351802
 C                 -2.06308652    0.45322711   -1.40660695
 C                 -2.24319729   -0.15551784    0.98790562
 O                 -2.67517742   -1.15805170    1.51334457
 O                 -1.65342353    1.30697439   -2.16301197
 H                  2.30070689    0.54361625    2.61788736
 C                  3.03810998    0.35860683    0.58463406
 C                  4.25076814    1.04070594    0.76914682
 C                  2.93142283   -0.47877665   -0.54408593
 C                  5.30261609    0.94253018   -0.14404216
 H                  4.37431243    1.67652037    1.64284438
 C                  3.96946538   -0.59149655   -1.46009371
 H                  2.04055493   -1.08222116   -0.67594425
 C                  5.16135002    0.12656052   -1.27478319
 H                  6.21590938    1.49747484    0.03629433
 H                  3.88530220   -1.24375260   -2.32419109
 Cl                 5.91006286   -0.01075874   -2.02676224


