%nprocshared=20
%mem=41GB
%chk=ts1-2
#p opt=(modredundant,loose) bp86 genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

preopt

1 1
 C                  0.08490545   -2.53826745    1.12576887
 H                  1.06150511   -3.02029693    0.98322555
 H                 -0.77623522   -3.11089240    0.75278109
 C                  0.00599347   -1.14275594    1.27295840
 C                 -0.01707069   -0.33486851    2.33776754
 C                 -0.10267957   -0.95069275    3.76490836
 H                  0.49046790   -0.31576502    4.44547959
 H                 -1.15878888   -0.91062538    4.09294097
 C                  0.41551845   -2.34635430    3.73277641
 H                  1.48945342   -2.48804685    3.91104244
 C                 -0.32524307   -3.40117714    3.27692071
 H                  0.10260475   -4.40565431    3.19380362
 H                 -1.41121945   -3.31224465    3.15255761
 Au                -0.00112839   -0.56783467   -0.74778858
 P                  0.00102218    0.24900586   -2.92894681
 C                 -1.63778991    0.86627541   -3.48946012
 C                  1.15762589    1.65839032   -3.17015043
 C                  0.49957614   -1.00649704   -4.17845953
 H                 -0.20204917   -1.85563373   -4.14381889
 H                  0.48841174   -0.55748229   -5.18660157
 H                  1.51351777   -1.36968908   -3.94550100
 H                 -2.37122724    0.04497816   -3.44813191
 H                 -1.56092746    1.24398787   -4.52343392
 H                 -1.97106701    1.67789941   -2.82269982
 H                  0.87830608    2.48156567   -2.49284501
 H                  1.11081700    2.00696878   -4.21607977
 H                  2.18356015    1.33294379   -2.93347653
 C                 -0.01167336    1.20209613    2.24127640
 C                 -1.21746790    1.90192496    2.18864016
 C                  1.19863664    1.89455286    2.20661324
 C                 -1.21285344    3.29385296    2.10068066
 H                 -2.17147752    1.35566369    2.21521186
 C                  1.20341858    3.28696787    2.11962214
 H                  2.14908187    1.34314768    2.24826912
 C                 -0.00204387    3.98666573    2.06651652
 H                 -2.16322892    3.84549454    2.05855541
 H                  2.15784469    3.83269814    2.09272417
 H                  0.00134406    5.08415512    1.99722073

1 11 F

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


--link1--
%nprocshared=20
%mem=41GB
%chk=ts1-2
#p opt=(calcfc,ts,noeigentest,modredundant,maxstep=4) freq=noraman bp86 genecp guess=read geom=checkpoint scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

ts opt freq

1 1

1 11 A

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD












