%nprocshared=20
%mem=41GB
%chk=ts1-2
#p opt=(modredundant,loose) bp86 genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

preopt

1 1
 C                 -0.13187230   -1.49424402    2.36082448
 H                  0.80386037   -2.01520776    2.61097691
 H                 -1.06928302   -2.03586458    2.55494962
 C                 -0.10534071   -0.21258787    1.94430811
 C                 -0.10529992    1.08276876    2.20392027
 H                 -0.06962337    1.80675739    1.38009625
 C                 -0.16839921    1.64284967    3.62190830
 H                  0.47988685    2.54277442    3.64002336
 H                 -1.20147128    2.00238199    3.79737555
 C                  0.25169478    0.66898376    4.69322617
 H                  0.61365325    1.11505201    5.63060998
 C                  0.21017462   -0.66742958    4.55985440
 H                  1.13926039   -1.19724622    4.79693625
 H                 -0.77019205   -1.15580796    4.62918179
 Au                -0.03139711   -0.28068255   -0.25319400
 P                  0.04941283    0.24918462   -2.51042645
 C                 -1.43930358    1.15437196   -3.09057235
 C                  1.48692434    1.30749423   -2.94258360
 C                  0.18130937   -1.24279703   -3.57402955
 H                 -0.68830710   -1.89583442   -3.39787220
 H                  0.20876015   -0.93886493   -4.63446376
 H                  1.10260431   -1.79181929   -3.32166643
 H                 -2.33252408    0.52983042   -2.92882840
 H                 -1.33732727    1.38631496   -4.16449940
 H                 -1.54461911    2.08974273   -2.51800323
 H                  1.42380242    2.25510380   -2.38402696
 H                  1.48273820    1.51428326   -4.02645687
 H                  2.41863631    0.78809732   -2.66674745

1 12 F

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


--link1--
%nprocshared=20
%mem=41GB
%chk=ts1-2
#p opt=(calcfc,ts,noeigentest,modredundant,maxstep=4) freq=noraman bp86 genecp guess=read geom=checkpoint scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

ts opt freq

1 1

1 12 A

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD








