%nprocshared=20
%mem=41GB
%chk=ts1-4
#p opt=(modredundant,loose) bp86 genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

preopt

1 1
 Au                 0.04945261   -0.49548567    0.03302484
 C                  1.10400558    1.94743453    0.12551553
 C                 -0.12793971    1.61168450    0.13705023
 C                  0.08644599    4.38728346    0.06153182
 C                  1.31400238    4.31583115    0.64885660
 C                 -1.41207691    2.36521838    0.17086624
 H                 -2.16597897    1.87396432    0.80832998
 H                 -1.82273809    2.39272211   -0.85543277
 C                 -1.13758428    3.82909635    0.70050751
 P                 -0.01251741   -2.80700416   -0.07584020
 C                  0.85895983   -3.49974016   -1.53908476
 C                  0.74772121   -3.63079492    1.38146757
 C                 -1.72729886   -3.46274884   -0.17021516
 H                 -2.22386353   -3.05635207   -1.06600284
 H                 -1.70586418   -4.56461578   -0.22622526
 H                 -2.28803655   -3.14869660    0.72488312
 H                  0.40052137   -3.10314973   -2.45928665
 H                  0.78509418   -4.60086983   -1.53161493
 H                  1.91880987   -3.19993106   -1.50719730
 H                  1.80843139   -3.34086725    1.45221911
 H                  0.66929093   -4.72639529    1.27532842
 H                  0.22493809   -3.30806962    2.29616265
 H                 -2.03338105    4.43121529    0.46874057
 H                 -1.01601304    3.77808866    1.79621867
 H                  0.00769164    4.71975597   -0.95245032
 H                  1.41960460    4.04993889    1.67989951
 H                  2.19710548    4.64139957    0.13990266
 C                  2.62591083    1.77283494   -0.03234327
 C                  3.20325682    1.80106596   -1.30212516
 C                  3.42717949    1.58658400    1.09407905
 C                  4.58148599    1.64239853   -1.44541070
 H                  2.57118379    1.94715152   -2.19003534
 C                  4.80596669    1.42883830    0.95099851
 H                  2.97232772    1.56448548    2.09495394
 C                  5.38318599    1.45657741   -0.31848383
 H                  5.03655110    1.66401173   -2.44628288
 H                  5.43753218    1.28241531    1.83934505
 H                  6.46985389    1.33155452   -0.43170265

2 4 F
2 5 F

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


--link1--
%nprocshared=20
%mem=41GB
%chk=ts1-4
#p opt=(calcfc,ts,noeigentest,modredundant,maxstep=4) freq=noraman bp86 genecp guess=read geom=checkpoint scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

ts opt freq

1 1

2 4 A
2 5 A

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



