%nprocshared=20
%mem=41GB
#p opt freq=noraman genecp scrf=(solvent=dichloromethane,pcm) nosymm bp86
empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                 0.10483104   -0.64456727   -0.04663951
 C                  0.77952512    2.77720365    0.59794349
 C                  0.42893832    1.51729479   -0.12703295
 C                  0.27305115    4.06571570   -0.10497766
 H                  0.89620418    4.93800832   -0.32809221
 C                 -0.81076258    4.88940850    0.73082419
 C                  0.16784301    2.15304457   -1.43829823
 H                 -0.42906950    1.48397063   -2.06330384
 H                  1.15678598    2.23490182   -1.90762272
 C                 -0.48778580    3.56603320   -1.44093127
 P                 -0.14806479   -2.93455020    0.19416593
 C                 -1.65150513   -3.53993158   -0.65798508
 C                  1.23931350   -3.89656636   -0.51774956
 C                 -0.29902149   -3.48887765    1.93195490
 H                 -1.15183251   -2.98838446    2.39657143
 H                 -0.44416342   -4.57368363    1.96457954
 H                  0.61011525   -3.22531134    2.47937997
 H                 -2.52960613   -3.06956759   -0.20814668
 H                 -1.72672548   -4.62801694   -0.56235253
 H                 -1.59260361   -3.25988566   -1.71250592
 H                  1.34022495   -3.65663191   -1.57984756
 H                  1.04919813   -4.96825759   -0.40060079
 H                  2.16783975   -3.63176568   -0.00461404
 H                 -0.29776949    3.96489496   -2.41545839
 H                 -1.54936113    3.48588559   -1.33353400
 C                 -0.14716418    6.22523528    1.11397428
 H                  0.11459343    6.76118135    0.22563607
 H                 -0.83031200    6.80923896    1.69461939
 H                  0.73529750    6.03342450    1.68788195
 C                 -2.34412498    4.80745483    0.84780007
 H                 -2.76334395    4.58134353   -0.11033830
 H                 -2.60817736    4.03826701    1.54316072
 H                 -2.72624134    5.74581218    1.19185321
 C                  1.61411088    2.79018704    1.89212201
 C                  3.00689834    2.83386917    1.82351887
 C                  0.97765255    2.75838885    3.13287089
 C                  3.76299777    2.84506596    2.99544464
 H                  3.50839146    2.85815359    0.84517501
 C                  1.73380666    2.77057908    4.30525830
 H                 -0.12007802    2.72413880    3.18712551
 C                  3.12627832    2.81377129    4.23674458
 H                  4.86083122    2.87886231    2.94144426
 H                  1.23170028    2.74591567    5.28339690
 H                  3.72264352    2.82266640    5.16063081

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

















