%nprocshared=20
%mem=41GB
#p opt freq=noraman genecp scrf=(solvent=dichloromethane,pcm) nosymm bp86
empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                 0.09266818   -1.33728209   -0.32605760
 C                  0.23735800    2.20124457   -0.51869588
 C                  0.38089926    0.75826795   -0.88350632
 C                  0.21340952    3.15700069   -1.74214756
 H                  0.84215357    4.04721829   -1.84791982
 C                 -1.16264391    3.94484318   -1.93571391
 H                 -2.09662204    3.70770309   -2.44299078
 C                  0.91447741    0.98844938   -2.24515093
 H                  0.79269610    0.08587033   -2.84939993
 H                  1.99250000    1.13457577   -2.09856083
 C                  0.36450825    2.20841196   -3.04240758
 P                 -0.22817195   -3.50151136    0.43495400
 C                 -0.96163966   -4.56927306   -0.85922175
 C                  1.32646779   -4.33338300    0.93315290
 C                 -1.34496604   -3.62545375    1.87973308
 H                 -2.31514824   -3.19376528    1.62275030
 H                 -1.47085098   -4.67563121    2.16295532
 H                 -0.91881007   -3.06924339    2.71919252
 H                 -1.94369115   -4.17461532   -1.13212902
 H                 -1.06651764   -5.59387098   -0.48782824
 H                 -0.31009906   -4.55371613   -1.73624064
 H                  2.01716220   -4.34998507    0.08552715
 H                  1.11504893   -5.35852494    1.25373965
 H                  1.78818932   -3.78088456    1.75604242
 H                  1.07604301    2.38125244   -3.82262836
 H                 -0.56484280    1.96054081   -3.51120020
 C                 -0.85437780    5.43365052   -1.69071449
 H                 -0.13517904    5.77158388   -2.40727169
 H                 -1.75337230    6.00520611   -1.79087974
 H                 -0.46039720    5.55859221   -0.70376522
 C                  0.17582245    2.69061806    0.94018279
 C                  1.35504997    2.94917468    1.63949843
 C                 -1.05877722    2.87548291    1.56238595
 C                  1.29960811    3.39184690    2.96093297
 H                  2.32824014    2.80259587    1.14893007
 C                 -1.11442780    3.31922888    2.88390114
 H                 -1.98829386    2.67191800    1.01130594
 C                  0.06448403    3.57728967    3.58326410
 H                  2.22905717    3.59506384    3.51240720
 H                 -2.08800615    3.46529060    3.37409029
 H                  0.02101876    3.92638432    4.62515662

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD















