%nprocshared=20
%mem=41GB
#p opt freq=noraman genecp scrf=(solvent=dichloromethane,pcm) nosymm bp86
empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                -0.02172156   -0.44086981   -0.05120131
 C                 -0.12928935    2.49811426    0.82855340
 C                 -0.10214904    1.56511031   -0.23803584
 C                  0.05008299    3.96440049    0.21308596
 C                 -1.28028650    3.60827643    0.69731078
 H                 -2.08638464    3.38216489   -0.00886962
 C                 -0.11068262    2.29046184   -1.55701251
 H                 -1.11585455    2.15811577   -2.01431777
 H                  0.57514034    1.79358807   -2.26658915
 C                  0.28739559    3.76753511   -1.28156845
 P                  0.06147827   -2.78902493    0.12151133
 C                 -1.03258196   -3.64760843   -1.08431951
 C                  1.74321424   -3.47257928   -0.18915386
 C                 -0.42577115   -3.45362334    1.76669013
 H                 -1.46347608   -3.15632763    1.98875230
 H                 -0.34898428   -4.55443440    1.76751884
 H                  0.23854427   -3.03611070    2.54063622
 H                 -2.07708622   -3.33928465   -0.91542519
 H                 -0.94589987   -4.74068227   -0.96216283
 H                 -0.73820062   -3.36525311   -2.10810938
 H                  2.07780753   -3.17532770   -1.19630566
 H                  1.72455772   -4.57353943   -0.11484837
 H                  2.44565507   -3.06434997    0.55556790
 H                 -1.60289932    3.93756926    1.68957575
 H                  1.35231671    3.92239767   -1.52121100
 H                 -0.30326904    4.48405610   -1.87778027
 C                  0.92564336    4.92950474    1.03379774
 H                  1.95828018    4.70969419    0.85988821
 H                  0.72055977    5.93691174    0.73719722
 H                  0.70643375    4.81246745    2.07454238
 C                  0.22662159    2.12696285    2.28016424
 C                 -0.78764205    1.87456844    3.20430587
 C                  1.56292987    2.04301175    2.67103576
 C                 -0.46558620    1.53896560    4.51917183
 H                 -1.84107298    1.94158880    2.89603110
 C                  1.88526513    1.70635440    3.98601549
 H                  2.36245600    2.24173198    1.94275198
 C                  0.87129240    1.45447079    4.91011016
 H                 -1.26499288    1.34062553    5.24780528
 H                  2.93897848    1.63983579    4.29381032
 H                  1.12497934    1.18978547    5.94687482

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD





