%nprocshared=20
%mem=41GB
#p opt freq=noraman genecp scrf=(solvent=dichloromethane,pcm) nosymm bp86
empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                 0.22716400   -0.25865500    0.06796700
 C                  0.94014800    1.66156600    0.04968200
 C                  0.21025700    2.77798900   -0.13257000
 C                 -0.33510700    5.04778300    0.35780500
 C                  0.76881500    4.20642700   -0.02893000
 H                  1.75266900    4.40881400    0.42773600
 C                 -1.28186400    2.96425500   -0.40251700
 H                 -1.89156200    2.13822600   -0.00611500
 H                 -1.46863200    3.03136300   -1.49196600
 C                 -1.60593900    4.33025400    0.25152100
 P                 -0.53345400   -2.47495800    0.06553300
 C                 -2.29527400   -2.67318500    0.57040300
 C                 -0.42741600   -3.30279400   -1.57774000
 C                  0.39904200   -3.58684700    1.20205500
 H                  0.31784800   -3.20459000    2.23266800
 H                 -0.00679700   -4.61208400    1.15510800
 H                  1.46211300   -3.59702300    0.91068400
 H                 -2.43018600   -2.26790900    1.58662200
 H                 -2.58322600   -3.73858700    0.55708300
 H                 -2.93822500   -2.10887500   -0.12493700
 H                 -1.04690200   -2.75134400   -2.30381600
 H                 -0.78023200   -4.34625000   -1.50872500
 H                  0.61924800   -3.29046700   -1.92327100
 H                  0.87335400    4.54636800   -1.10720100
 H                 -2.44152800    4.92269700   -0.16547000
 H                 -1.88573400    4.22006800    1.33647800
 C                 -0.20130106    6.48540424    0.89347388
 H                  0.64115429    6.95984131    0.43513072
 H                 -1.08951027    7.03588473    0.66335298
 H                 -0.06257817    6.45935294    1.95412334
 C                  2.45032499    1.86679567    0.27069385
 C                  3.31216359    1.93804384   -0.82412547
 C                  2.95653844    1.98156069    1.56534634
 C                  4.67998072    2.12334103   -0.62421800
 H                  2.91286255    1.84675914   -1.84464866
 C                  4.32461912    2.16790451    1.76544911
 H                  2.27739378    1.92560706    2.42834155
 C                  5.18637301    2.23867055    0.67095863
 H                  5.35943485    2.17888123   -1.48709335
 H                  4.72340755    2.25877036    2.78632394
 H                  6.26487654    2.38482473    0.82832902

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD





