%nprocshared=20
%mem=41GB
#p opt freq=noraman genecp scrf=(solvent=dichloromethane,pcm) nosymm bp86
empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                 0.08572976   -0.65574341    0.27325417
 C                  0.27511384    1.31577026    0.68754997
 C                 -0.11593728    2.35906772   -0.12809450
 C                  1.04561762    3.63942614   -0.42971581
 H                  2.04278228    3.57464788    0.01717646
 C                 -0.13572799    3.85328021    0.38055301
 C                 -0.38356739    2.36232719   -1.63890134
 H                 -1.39700867    2.70164367   -1.91004863
 H                 -0.18659640    1.38096046   -2.09622343
 C                  0.75083964    3.40929101   -1.90822228
 P                 -0.11488907   -2.95437895   -0.18417638
 C                 -0.02432048   -4.01892048    1.31545528
 C                 -1.69630421   -3.42474242   -1.00099054
 C                  1.19914256   -3.59323223   -1.30540573
 H                  2.18621426   -3.42776137   -0.84414084
 H                  1.05125707   -4.67167490   -1.48660766
 H                  1.15608949   -3.04913895   -2.26297736
 H                  0.94004767   -3.85453680    1.82326723
 H                 -0.11874147   -5.08201890    1.03537419
 H                 -0.84053646   -3.74485057    2.00370453
 H                 -2.54027543   -3.15629216   -0.34516270
 H                 -1.71156421   -4.51054994   -1.19760109
 H                 -1.79465963   -2.87588417   -1.95178350
 H                  1.61169430    2.97589807   -2.43674428
 H                  0.42812454    4.33065095   -2.42452280
 H                 -0.96378511    4.38889659   -0.03458131
 H                  0.00110419    3.97141326    1.43517215
 C                  0.89929632    1.75920798    2.02372332
 C                  0.08033146    2.03084498    3.12007241
 C                  2.28335146    1.88917981    2.13794597
 C                  0.64533567    2.43300928    4.33013681
 H                 -1.01084537    1.92902622    3.02947522
 C                  2.84875214    2.29050479    3.34859465
 H                  2.92898333    1.67495575    1.27400351
 C                  2.03001496    2.56255157    4.44458598
 H                 -0.00015884    2.64774004    5.19415304
 H                  3.94007809    2.39249882    3.43847847
 H                  2.47527634    2.87960178    5.39879655

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD








