%nprocshared=20
%mem=41GB
#p opt freq=noraman genecp scrf=(solvent=dichloromethane,pcm) nosymm bp86
empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                 0.27089209   -0.64002709    0.25175309
 C                  1.15324753   -1.93136498   -1.29323645
 C                  0.08856298   -1.65653264   -1.88273591
 C                 -0.46943943    1.06466474   -3.06702409
 H                 -0.06028010    0.93351304   -4.07954785
 C                  0.02716708    2.02318945   -2.26462881
 H                 -0.36739940    2.17614631   -1.25225892
 C                 -1.09902822   -1.38237358   -2.69637430
 H                 -1.92586766   -2.03913752   -2.37000740
 H                 -0.84025745   -1.67544206   -3.73315328
 C                 -1.56018721    0.10795189   -2.66448723
 P                 -0.26894537    0.59819537    2.12354458
 C                 -1.09124702    2.18718589    1.70533403
 C                 -1.41258800   -0.27152123    3.26788582
 H                  2.12450367   -2.36593852   -1.09131211
 C                  1.20967264    1.04066297    3.11946818
 H                  1.91350744    1.61059015    2.49197481
 H                  0.90585474    1.65109031    3.98665834
 H                  1.70357191    0.11982834    3.46909816
 H                 -0.38802927    2.82487909    1.14596305
 H                 -1.39858681    2.70251368    2.63153627
 H                 -1.97629262    1.98874798    1.07957570
 H                 -2.35432532   -0.49494150    2.74115805
 H                 -1.62052541    0.36593147    4.14459169
 H                 -0.95170041   -1.21672635    3.59668802
 H                 -2.42056874    0.18038706   -3.35621182
 H                 -1.92959122    0.34932963   -1.65040871
 C                  1.15129757    2.96993962   -2.72462312
 H                  0.80839125    3.55518202   -3.55215353
 H                  1.42408220    3.61805549   -1.91812802
 H                  2.00247066    2.39438795   -3.02319413

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




