%mem=3200mb
%nproc=4
#p B3LYP/genecp scf=(xqc,maxcyc=1000,conver=8)
5D 7F scf=nosym empiricaldispersion=gd3 scrf=(pcm)

pdph3-H2eta1_vacuum_aq

0 1
 Pd	-0.558505000	-0.001997000	 0.000595000
 P	 1.692030000	 0.001863000	 0.000392000
 H	 2.410069000	-1.051009000	-0.617896000
 H	 2.392699000	 1.065616000	-0.619098000
 H	 2.422543000	 0.008702000	 1.213981000
 H	-2.452501000	 0.019938000	-0.004514000
 H	-3.206450000	 0.011061000	-0.001975000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


