%nprocshared=20
%mem=20GB
#p opt freq=noraman b3lyp genecp scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ptme32_dichloromethane 

1 1
 P	 0.113093000	-1.890244000	 0.110497000
 P	 0.189014000	 2.783644000	-0.085758000
 Pt	 0.203890000	 0.445466000	 0.019632000
 C	 1.872056000	 0.472172000	 1.207698000
 H	 2.497868000	 1.333421000	 0.968504000
 H	 1.519811000	 0.543275000	 2.240488000
 H	 2.452811000	-0.441837000	 1.075996000
 C	-1.405912000	-2.553843000	-0.656814000
 H	-1.412873000	-3.645167000	-0.598192000
 H	-2.280574000	-2.158195000	-0.137377000
 H	-1.449797000	-2.248406000	-1.703876000
 C	 0.129424000	-2.574772000	 1.802582000
 H	 0.081667000	-3.666074000	 1.772618000
 H	 1.046267000	-2.268157000	 2.309398000
 H	-0.725921000	-2.188826000	 2.359782000
 C	 1.482256000	-2.748159000	-0.739479000
 H	 2.432736000	-2.450543000	-0.292732000
 H	 1.365558000	-3.831041000	-0.649756000
 H	 1.487882000	-2.470288000	-1.794897000
 C	-1.319692000	 3.430271000	-0.886859000
 H	-2.198710000	 3.107479000	-0.326051000
 H	-1.291559000	 4.522379000	-0.918859000
 H	-1.388234000	 3.041172000	-1.904472000
 C	 0.253990000	 3.607023000	 1.541686000
 H	 1.168443000	 3.314014000	 2.060669000
 H	 0.241100000	 4.692764000	 1.419226000
 H	-0.604576000	 3.298808000	 2.140825000
 C	 1.571654000	 3.521238000	-1.022026000
 H	 1.490251000	 4.611034000	-1.024073000
 H	 2.518202000	 3.231901000	-0.561647000
 H	 1.553958000	 3.154177000	-2.049684000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
-Pt  0
sdd
****
-Br     0
S   2   1.00
1.1590000             -3.0378769
0.7107000              3.3703735
S   1   1.00
0.1905000              1.0000000
P   2   1.00
2.6910000             -0.1189800
0.4446000              1.0424471
P   1   1.00
0.1377000              1.0000000
P   1   1.00
0.0376                 1.0
D   1   1.00
0.4340                 1.0
****

-BR     0
BR-ECP     3     28
f potential
4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

