%nprocshared=12
%mem=20GB
#p opt freq=noraman b3lyp genecp scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3pdme32_dichloromethane 

1 1
 Pd	 0.138811000	 0.441599000	-0.023430000
 P	 0.102984000	-1.907664000	 0.126401000
 P	 0.153787000	 2.793347000	-0.098582000
 C	 1.764817000	 0.485366000	 1.212293000
 H	 2.373564000	 1.367110000	 1.011033000
 H	 1.365493000	 0.523033000	 2.228405000
 H	 2.368567000	-0.411823000	 1.073994000
 C	 1.552224000	 3.548011000	-1.005462000
 H	 1.466881000	 4.637690000	-0.996599000
 H	 2.493838000	 3.258111000	-0.535303000
 H	 1.552831000	 3.193877000	-2.038036000
 C	 0.196518000	 3.621222000	 1.531583000
 H	 1.098788000	 3.325108000	 2.069831000
 H	 0.192939000	 4.706933000	 1.406326000
 H	-0.675016000	 3.321744000	 2.116718000
 C	-1.332593000	 3.482983000	-0.916250000
 H	-1.392533000	 3.112176000	-1.941396000
 H	-2.228060000	 3.168469000	-0.376741000
 H	-1.284613000	 4.575008000	-0.930332000
 C	-1.392969000	-2.650830000	-0.623981000
 H	-1.365499000	-3.738939000	-0.522573000
 H	-2.284339000	-2.264729000	-0.125789000
 H	-1.441906000	-2.389267000	-1.682827000
 C	 1.490060000	-2.779342000	-0.688969000
 H	 2.435758000	-2.457264000	-0.248924000
 H	 1.385276000	-3.860104000	-0.563338000
 H	 1.499619000	-2.538660000	-1.753693000
 C	 0.123576000	-2.566269000	 1.832975000
 H	 0.095028000	-3.658791000	 1.819737000
 H	 1.031497000	-2.237636000	 2.341938000
 H	-0.741406000	-2.188390000	 2.381236000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
-Pd  0
sdd
****
-Br     0
S   2   1.00
1.1590000             -3.0378769
0.7107000              3.3703735
S   1   1.00
0.1905000              1.0000000
P   2   1.00
2.6910000             -0.1189800
0.4446000              1.0424471
P   1   1.00
0.1377000              1.0000000
P   1   1.00
0.0376                 1.0
D   1   1.00
0.4340                 1.0
****

-BR     0
BR-ECP     3     28
f potential
4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

