%nprocshared=20
%mem=40GB
#p opt freq=noraman b3lyp/genecp
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

test of the TS AuPMeCH3-CH3

1 1
 Au                -0.28649100    1.48281800    1.15790600
 P                  1.83184300    0.98971600    0.03850700
 C                  2.31309500    2.28050000   -1.15745900
 H                  2.38375400    3.24230900   -0.64603000
 H                  3.27988000    2.03805600   -1.60521600
 H                  1.55763900    2.35328200   -1.94184200
 C                  3.22731600    0.89541900    1.20967700
 H                  3.05819000    0.08041200    1.91567600
 H                  4.16379400    0.72341300    0.67365400
 H                  3.29436600    1.83268000    1.76546700
 C                  1.86988900   -0.57643700   -0.89742400
 H                  2.85358300   -0.71707000   -1.35217400
 H                  1.65889600   -1.41009800   -0.22521100
 H                  1.10899600   -0.55218700   -1.67977100
 C                 -2.11476700    1.83276600    2.09604000
 H                 -2.65799500    0.89090100    1.95417100
 H                 -1.99159100    2.03612900    3.16059300
 H                 -2.65697200    2.65160600    1.62100700
 C                  0.15979500    3.41091700    1.79594000
 H                  1.15858700    3.61556700    1.41938000
 H                 -0.58638000    4.07321100    1.36582100
 H                  0.12155200    3.40089600    2.88181800

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
-Au  0
sdd
****
-Br     0
S   2   1.00
      1.1590000             -3.0378769
      0.7107000              3.3703735
S   1   1.00
      0.1905000              1.0000000
P   2   1.00
      2.6910000             -0.1189800
      0.4446000              1.0424471
P   1   1.00
      0.1377000              1.0000000
P   1   1.00
      0.0376                 1.0
D   1   1.00
      0.4340                 1.0
****

-BR     0
BR-ECP     3     28
f potential
  4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
  4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
  5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
  5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd



