%nprocshared=24
%mem=120GB
#p opt freq=noraman b3lyp genecp scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ptph32_dichloromethane 

1 1
 P	 0.121960000	-1.876410000	 0.205251000
 P	 0.197083000	 2.775279000	 0.033219000
 C	 0.265523000	 3.701194000	 1.609763000
 C	 1.487828000	 3.757984000	 2.295834000
 C	-0.869388000	 4.297677000	 2.168866000
 C	 1.569588000	 4.408423000	 3.523861000
 H	 2.376136000	 3.305698000	 1.869031000
 C	-0.781851000	 4.945258000	 3.401959000
 H	-1.820583000	 4.264809000	 1.650446000
 C	 0.434339000	 5.001695000	 4.080825000
 H	 2.519590000	 4.452920000	 4.045799000
 H	-1.665972000	 5.408245000	 3.827381000
 H	 0.500062000	 5.507602000	 5.038240000
 C	-1.425779000	 3.142469000	-0.733831000
 C	-2.537673000	 2.401252000	-0.304043000
 C	-1.579302000	 4.092046000	-1.750392000
 C	-3.786802000	 2.611950000	-0.882606000
 H	-2.429160000	 1.661578000	 0.483493000
 C	-2.832682000	 4.299546000	-2.325252000
 H	-0.729210000	 4.667863000	-2.097924000
 C	-3.935636000	 3.561114000	-1.894658000
 H	-4.639644000	 2.032158000	-0.546225000
 H	-2.945472000	 5.037240000	-3.112663000
 H	-4.907593000	 3.722727000	-2.348726000
 C	 1.472465000	 3.520305000	-1.038168000
 C	 2.083999000	 2.717669000	-2.009709000
 C	 1.818683000	 4.873852000	-0.936529000
 C	 3.028173000	 3.267147000	-2.875117000
 H	 1.827775000	 1.666057000	-2.084316000
 C	 2.766048000	 5.417425000	-1.801958000
 H	 1.352836000	 5.503307000	-0.186462000
 C	 3.370211000	 4.615995000	-2.771979000
 H	 3.500195000	 2.640380000	-3.624244000
 H	 3.031035000	 6.466078000	-1.718752000
 H	 4.108721000	 5.041320000	-3.443393000
 C	-0.191953000	-2.636967000	 1.837775000
 C	-0.958620000	-3.801655000	 1.970221000
 C	 0.364853000	-2.039089000	 2.975946000
 C	-1.158462000	-4.365322000	 3.229506000
 H	-1.399999000	-4.270106000	 1.097440000
 C	 0.165945000	-2.609765000	 4.231701000
 H	 0.946970000	-1.129300000	 2.885112000
 C	-0.595205000	-3.772455000	 4.360158000
 H	-1.754081000	-5.266877000	 3.325929000
 H	 0.599346000	-2.141976000	 5.109335000
 H	-0.753281000	-4.212349000	 5.339235000
 C	-1.316834000	-2.313516000	-0.838840000
 C	-2.466188000	-1.515007000	-0.736070000
 C	-1.298812000	-3.393542000	-1.727878000
 C	-3.586332000	-1.800890000	-1.512277000
 H	-2.487510000	-0.669259000	-0.054785000
 C	-2.424897000	-3.676531000	-2.500886000
 H	-0.414071000	-4.013800000	-1.818366000
 C	-3.567516000	-2.883108000	-2.394329000
 H	-4.469978000	-1.176768000	-1.431472000
 H	-2.407640000	-4.517235000	-3.186396000
 H	-4.440240000	-3.104952000	-2.999419000
 C	 1.563492000	-2.737784000	-0.513653000
 C	 1.979351000	-4.000314000	-0.077492000
 C	 2.254344000	-2.098188000	-1.552226000
 C	 3.073181000	-4.620274000	-0.681753000
 H	 1.457375000	-4.502858000	 0.728880000
 C	 3.341626000	-2.724179000	-2.156388000
 H	 1.947844000	-1.109859000	-1.879752000
 C	 3.752469000	-3.985960000	-1.721744000
 H	 3.392912000	-5.598478000	-0.338575000
 H	 3.872466000	-2.224349000	-2.959643000
 H	 4.603582000	-4.470055000	-2.188942000
 Pt	 0.292846000	 0.447575000	 0.207867000
 C	 2.205730000	 0.471212000	 0.942807000
 H	 2.809408000	 1.122211000	 0.308062000
 H	 2.159063000	 0.875166000	 1.956457000
 H	 2.633938000	-0.530238000	 0.957243000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
-Pt  0
sdd
****
-Br     0
S   2   1.00
1.1590000             -3.0378769
0.7107000              3.3703735
S   1   1.00
0.1905000              1.0000000
P   2   1.00
2.6910000             -0.1189800
0.4446000              1.0424471
P   1   1.00
0.1377000              1.0000000
P   1   1.00
0.0376                 1.0
D   1   1.00
0.4340                 1.0
****

-BR     0
BR-ECP     3     28
f potential
4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

