%mem=16000MB
%nprocshared=12
#p opt freq b3lyp 6-311+g(d) scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch4_6311+Gd_new

0 1
 C	-0.000003000	 0.000051000	-0.665589000
 H	-0.000001000	 1.029093000	-1.029458000
 H	 0.891209000	-0.514494000	-1.029354000
 H	-0.891212000	-0.514494000	-1.029363000
 H	-0.000009000	 0.000129000	 0.425915000



