%nprocshared=12
%mem=20GB
#p opt freq=noraman b3lyp genecp scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

pdme32_ch2cl2      

0 1
 Pd	 0.030208000	 0.425542000	 0.028191000
 P	 0.073654000	-1.891533000	 0.018397000
 P	-0.013179000	 2.742624000	 0.037578000
 C	 0.093676000	-2.718477000	-1.629224000
 H	 0.113758000	-3.806670000	-1.517109000
 H	-0.795728000	-2.433596000	-2.195492000
 H	 0.974960000	-2.400481000	-2.190531000
 C	-1.334662000	-2.758444000	 0.833317000
 H	-1.210288000	-3.843742000	 0.771601000
 H	-1.391059000	-2.463990000	 1.883513000
 H	-2.271413000	-2.477737000	 0.346922000
 C	 1.512550000	-2.700820000	 0.839144000
 H	 1.433223000	-3.790297000	 0.776377000
 H	 2.439139000	-2.381434000	 0.357208000
 H	 1.552102000	-2.405000000	 1.889720000
 C	-1.453444000	 3.551444000	-0.781159000
 H	-1.373643000	 4.640969000	-0.719919000
 H	-1.495546000	 3.254314000	-1.831262000
 H	-2.379030000	 3.232945000	-0.296690000
 C	-0.030493000	 3.570645000	 1.684753000
 H	 0.859909000	 3.286176000	 2.249655000
 H	-0.050728000	 4.658751000	 1.571811000
 H	-0.910822000	 3.253145000	 2.247822000
 C	 1.394044000	 3.609113000	-0.779696000
 H	 1.269410000	 4.694431000	-0.718918000
 H	 2.331209000	 3.329129000	-0.293660000
 H	 1.449820000	 3.313658000	-1.829635000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
-Pd  0
sdd
****
-Br     0
S   2   1.00
1.1590000             -3.0378769
0.7107000              3.3703735
S   1   1.00
0.1905000              1.0000000
P   2   1.00
2.6910000             -0.1189800
0.4446000              1.0424471
P   1   1.00
0.1377000              1.0000000
P   1   1.00
0.0376                 1.0
D   1   1.00
0.4340                 1.0
****

-BR     0
BR-ECP     3     28
f potential
4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

