%nprocshared=20
%mem=40GB
#p opt freq=noraman b3lyp genecp scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ptph32_dichloromethane 

0 1
 P	 0.058576000	-1.857056000	 0.025423000
 P	-0.057121000	 2.705237000	 0.005646000
 C	 1.341842000	 3.510033000	 0.890379000
 C	 2.601851000	 2.901018000	 0.805724000
 C	 1.201625000	 4.696474000	 1.619242000
 C	 3.706321000	 3.478912000	 1.428156000
 H	 2.715103000	 1.971252000	 0.256920000
 C	 2.307616000	 5.268176000	 2.249741000
 H	 0.234213000	 5.179649000	 1.698569000
 C	 3.560878000	 4.663650000	 2.152843000
 H	 4.677517000	 3.000560000	 1.354697000
 H	 2.188168000	 6.186924000	 2.814643000
 H	 4.419557000	 5.110106000	 2.643434000
 C	-1.561782000	 3.439336000	 0.769168000
 C	-2.117239000	 2.784527000	 1.877244000
 C	-2.155055000	 4.617107000	 0.300104000
 C	-3.240923000	 3.308031000	 2.513664000
 H	-1.672548000	 1.861605000	 2.236358000
 C	-3.285464000	 5.134412000	 0.933751000
 H	-1.740503000	 5.134818000	-0.557718000
 C	-3.828127000	 4.483671000	 2.041923000
 H	-3.662707000	 2.794271000	 3.371333000
 H	-3.740202000	 6.046368000	 0.560924000
 H	-4.707475000	 4.887417000	 2.532920000
 C	-0.002178000	 3.437835000	-1.682234000
 C	-0.672844000	 2.759936000	-2.710035000
 C	 0.664897000	 4.633780000	-1.971276000
 C	-0.686617000	 3.278476000	-4.003221000
 H	-1.177654000	 1.822602000	-2.497631000
 C	 0.656985000	 5.146406000	-3.269167000
 H	 1.191640000	 5.169408000	-1.189412000
 C	-0.020016000	 4.472491000	-4.285643000
 H	-1.209308000	 2.746553000	-4.791447000
 H	 1.179730000	 6.072775000	-3.483991000
 H	-0.024205000	 4.872201000	-5.294372000
 C	-1.362084000	-2.654878000	 0.880941000
 C	-1.932528000	-3.858098000	 0.449846000
 C	-1.875354000	-2.021181000	 2.021256000
 C	-2.998472000	-4.421132000	 1.152680000
 H	-1.550598000	-4.360498000	-0.431763000
 C	-2.933990000	-2.590081000	 2.726363000
 H	-1.449398000	-1.078942000	 2.351745000
 C	-3.498648000	-3.791042000	 2.292259000
 H	-3.436147000	-5.352666000	 0.808937000
 H	-3.323298000	-2.092106000	 3.608355000
 H	-4.327896000	-4.230478000	 2.836837000
 C	 0.053365000	-2.605895000	-1.655922000
 C	-0.698528000	-1.967756000	-2.652351000
 C	 0.751832000	-3.777695000	-1.968901000
 C	-0.760801000	-2.501897000	-3.937790000
 H	-1.228914000	-1.049044000	-2.421768000
 C	 0.694830000	-4.305824000	-3.259276000
 H	 1.340838000	-4.282631000	-1.211375000
 C	-0.062741000	-3.671743000	-4.244098000
 H	-1.346246000	-2.000658000	-4.701652000
 H	 1.242082000	-5.213260000	-3.492986000
 H	-0.105183000	-4.083451000	-5.247106000
 C	 1.543925000	-2.580974000	 0.835896000
 C	 1.505621000	-3.766613000	 1.578434000
 C	 2.764054000	-1.908757000	 0.677847000
 C	 2.672683000	-4.274982000	 2.150259000
 H	 0.570243000	-4.297834000	 1.714317000
 C	 3.929573000	-2.423553000	 1.241640000
 H	 2.798516000	-0.979364000	 0.117844000
 C	 3.885736000	-3.607728000	 1.980286000
 H	 2.632500000	-5.193360000	 2.726825000
 H	 4.869236000	-1.896697000	 1.111563000
 H	 4.791962000	-4.005079000	 2.425473000
 Pt	 0.000382000	 0.424138000	 0.029012000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
-Pt  0
sdd
****
-Br     0
S   2   1.00
1.1590000             -3.0378769
0.7107000              3.3703735
S   1   1.00
0.1905000              1.0000000
P   2   1.00
2.6910000             -0.1189800
0.4446000              1.0424471
P   1   1.00
0.1377000              1.0000000
P   1   1.00
0.0376                 1.0
D   1   1.00
0.4340                 1.0
****

-BR     0
BR-ECP     3     28
f potential
4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

