%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ph2-sime3-ts_6311+Gd_new

-1 1
 C                 -0.64882341   -0.81561264    1.97973699
 H                 -1.23213655   -1.73311399    1.89373027
 H                 -0.28886698   -0.53999895    0.98923379
 H                 -1.31503662   -0.03061049    2.34371520
 Si                -2.49846800   -0.35860600    0.36110800
 C                 -2.43440400   -1.28455500   -1.35546600
 H                 -1.44036500   -1.22587400   -1.81811300
 H                 -2.67161700   -2.35183700   -1.25307400
 H                 -3.15334700   -0.86001000   -2.07499000
 C                 -4.41524300   -0.52087200    0.70061800
 H                 -4.69170400   -1.52890100    1.03637400
 H                 -4.74501400    0.17195900    1.48669300
 H                 -5.01563300   -0.29989000   -0.19725800
 C                 -2.46022900    1.47073600   -0.32179300
 H                 -2.42924700    2.22566400    0.47402600
 H                 -1.57732800    1.63904200   -0.95330400
 H                 -3.34333100    1.68862300   -0.94379100
 H                  1.99470401   -0.25155174    3.16032636
 H                  1.84351470   -2.28516505    2.72056766
 P                  1.13430736   -1.33118920    3.50112632

