%nprocshared=24
%mem=40GB
#p opt=(calcfc,ts,noeigentest,maxstep=10) freq=noraman b3lyp/genecp
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

test of the TS Ph2-Rhmin-CH3

0 1
 C                 -1.53018000    1.82404600    0.28344100
 H                 -1.70319400    2.85245700    0.56700700
 H                 -1.00921200    1.64460500   -0.64796700
 H                 -2.30395800    1.12367800    0.56423800
 H                 -3.18515700    1.30490900   -2.27880700
 H                 -2.50014000    3.26353200   -2.27753800
 P                 -3.49196800    2.51086400   -1.57424600
 Rh                 0.11597088    1.44127153    1.72653161
 N                 -1.19140308    0.00907129    2.29488356
 N                 -0.89486823    2.38879993    3.12313153
 N                  1.19013113    2.95355986    1.07078987
 N                  1.02050867    0.60547311    0.12462828
 C                 -2.01167286    0.35771152    3.24351724
 C                 -1.13466675   -1.29274221    1.63011134
 C                 -1.87543177    1.76151578    3.71485865
 O                 -0.67894599    3.70225596    3.40894427
 C                  1.90457528    2.78624252   -0.00943294
 O                  1.11700438    4.19129965    1.63332463
 C                  1.82228085    1.39550231   -0.52917487
 C                  0.72553774   -0.79115680   -0.19516616
 C                 -3.05819963   -0.52122456    3.85969915
 H                 -0.39894670   -1.90616831    2.16436017
 H                 -2.09677686   -1.80804114    1.68252781
 C                 -0.72995589   -1.17636028    0.14506872
 C                 -2.74602332    2.38810227    4.76239324
 B                  0.69552230    4.21274430    3.07623386
 C                  2.72357770    3.87428915   -0.63650040
 C                  2.62351003    1.01868147   -1.73885231
 H                  1.38915826   -1.42103826    0.35959248
 H                 -4.05436083   -0.24305624    3.49801688
 H                 -2.89661536   -1.57482122    3.64101014
 H                 -3.06625744   -0.39840311    4.94513503
 H                 -0.89723042   -2.16439895   -0.29695376
 H                 -1.41348783   -0.48846240   -0.36258330
 H                 -3.73436537    1.92339421    4.74350890
 H                 -2.88356703    3.44273261    4.51443543
 C                 -2.13631699    2.26785538    6.17003972
 F                  1.64747829    3.51191324    3.84554916
 F                  0.65977300    5.56703481    3.41381664
 H                  2.80240437    3.69987122   -1.71191494
 H                  2.19992214    4.82341281   -0.50389121
 C                  4.12833245    3.97291513   -0.01640543
 H                  2.17064483    1.43816797   -2.64414656
 H                  3.63423831    1.42663952   -1.66831480
 H                  2.70250111   -0.05938884   -1.86408262
 H                 -2.79307309    2.73432324    6.90984293
 H                 -1.99487546    1.22164081    6.45540515
 H                 -1.16440828    2.76480447    6.21684243
 H                  4.68691028    3.04136040   -0.14360384
 H                  4.69800723    4.77642543   -0.49187059
 H                  4.06714721    4.18634030    1.05342270
 H                  0.89026603   -0.94928473   -1.24051785

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
****

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


