%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=6,maxcycles=500) freq b3lyp 6-311+g(d) scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3ph2-s-ts_6311+Gd_new

-2 1
 C	 0.024897000	 0.220945000	-0.021507000
 H	-0.991011000	 0.614749000	-0.053285000
 H	 0.465126000	 0.500964000	 0.935808000
 H	 0.594563000	 0.715793000	-0.807831000
 S	 0.074002000	 4.236510000	-0.191977000
 H	-1.331668000	-1.907001000	-0.092207000
 H	 0.395280000	-2.039269000	 1.043438000
 P	 0.051297000	-1.639221000	-0.275392000



