%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3h2o-OTf-ts_6311+Gd_aq_new

0 1
 S                  1.13669700    0.96338300   -0.80271900
 O                  1.63623900    2.06406100    0.03041800
 O                  1.48102600    0.97646600   -2.22785900
 O                  1.34332100   -0.40396500   -0.18143100
 C                  1.57592200   -0.62416900    1.74033100
 H                  2.57227500   -0.21930400    1.70901900
 H                  0.74182900    0.00404200    2.00215500
 H                  1.41954100   -1.68087500    1.60664100
 O                  1.81442322   -1.01589884    3.89199661
 H                  2.14592922   -0.20356984    4.30075561
 C                 -0.74001900    1.14315500   -0.75783700
 F                 -1.31530900    0.19550500   -1.50340900
 F                 -1.17823900    1.02657300    0.50146400
 F                 -1.09628600    2.34168200   -1.23032700
 H                  2.51825622   -1.67351984    3.98743661

