%mem=30000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/genecp
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ts-oTf-ch3-pt_6311+Gd_new

0 1
 C                  0.71654100   -0.27303100    0.46697300
 H                  1.21554300    0.22648600    1.28011700
 H                  0.21912700    0.31753300   -0.28563300
 H                  1.05714800   -1.26005600    0.20318200
 O                 -0.72416200   -0.88141900    1.34700900
 S                 -1.46126900    0.03706800    2.33728200
 O                 -2.30732900   -0.73889900    3.23625000
 O                 -0.59891100    1.08291600    2.88591900
 C                 -2.65648100    0.94827200    1.19537300
 F                 -3.38230300    1.82140900    1.90145700
 F                 -1.97527600    1.61738300    0.25437800
 F                 -3.48168700    0.08616300    0.59416000
 P                  2.85318500   -1.21038100   -2.23287300
 P                  2.72561000    2.68761100    0.30432900
 C                  3.44452100   -2.75218600   -1.41725600
 C                  1.23592200   -1.75206000   -2.92793600
 C                  3.91434200   -1.13917700   -3.73554400
 C                  3.46713000    2.64800000    1.98967500
 C                  3.58897200    4.12300300   -0.46139700
 C                  1.05558800    3.38044000    0.65058900
 H                  2.80675800   -2.98600500   -0.56140800
 H                  3.43012100   -3.59718300   -2.11230300
 H                  4.46383600   -2.60680100   -1.05223200
 H                  1.34763900   -2.66109800   -3.52649500
 H                  0.53042900   -1.94680600   -2.11672400
 H                  0.82317000   -0.95909100   -3.55581800
 H                  3.87213900   -2.08025500   -4.29215900
 H                  3.57971400   -0.32510100   -4.38260700
 H                  4.94878600   -0.94170100   -3.44505900
 H                  4.52117200    2.36892300    1.92225400
 H                  3.38489300    3.62360400    2.47825800
 H                  2.95394800    1.90210300    2.60123500
 H                  3.14059600    4.34432900   -1.43279800
 H                  3.51896000    5.00984200    0.17569100
 H                  4.64192800    3.87807500   -0.61880500
 H                  0.48610000    2.68559900    1.26985200
 H                  1.13419500    4.33641900    1.17723400
 H                  0.51752300    3.53371400   -0.28752700
 Pt                 2.78970100    0.70857600   -0.92673500

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
****

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


