%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3oTs-sime3-ts_6311+Gd_new

-1 1
 C                  1.02743800   -0.15545700    0.42040700
 H                  1.02113400   -0.99731400    1.09535400
 H                  0.85988200   -0.37871500   -0.62149700
 H                  0.61051000    0.76846500    0.78876900
 Si                -1.95682500   -0.35717700   -0.00836400
 C                 -2.33798500   -1.21856100   -1.70624700
 H                 -1.48396300   -1.15867300   -2.39324200
 H                 -2.56968100   -2.28415200   -1.58261100
 H                 -3.19750800   -0.75492800   -2.21529500
 C                 -3.71983500   -0.40362100    0.80618700
 H                 -4.02343500   -1.42504200    1.06820100
 H                 -3.75898800    0.18538100    1.73126600
 H                 -4.48786500    0.00144200    0.12870200
 C                 -1.89423800    1.49573000   -0.58176600
 H                 -1.83158000    2.18459300    0.27067800
 H                 -1.01858900    1.69477800   -1.21307100
 H                 -2.78536900    1.77819500   -1.16332200
 O                  2.70083200    0.21544300    0.28627400
 S                  3.45597300    0.62459000    1.60040700
 C                  5.08649600    1.00892900    0.98972700
 O                  3.54420100   -0.53062700    2.51747500
 O                  2.85343000    1.84715700    2.17103700
 F                  5.49800277    2.18313575    1.51355970
 F                  5.94406676    0.03042052    1.34971805
 F                  5.05193878    1.10422589   -0.35646181

