%mem=3000MB
%nprocshared=12
#p opt=(calcall,ts,noeigentest,maxstep=6,maxcycles=150) freq=noraman
b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane) nosymm
empiricaldispersion=gd3

ch3oTf-o-ts_6311+Gd5_new

-2 1
 C                  0.04050800   -1.46665300    0.36962100
 O                  1.45836500   -4.69741500    0.84930600
 H                  0.90002600   -0.96808100    0.79510800
 H                 -0.78910200   -1.72634600    1.01326500
 H                 -0.11119600   -1.42877400   -0.70095600
 O                 -0.59605100    1.33143400   -0.77106400
 S                 -1.49328300    2.14902000    0.06808500
 O                 -1.66284900    1.68395800    1.45876700
 O                 -2.73052200    2.60936300   -0.59633100
 C                 -0.51503500    3.75247400    0.28044200
 F                 -1.19899500    4.65169900    1.01622800
 F                  0.66134900    3.53143700    0.89832700
 F                 -0.24733800    4.32353500   -0.91084500

