%mem=30000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3oTs-ch3-ts_6311+Gd_new

0 1 
 C                  1.10250518   -0.04096730    0.33809574
 H                  1.67084218    0.64115070    0.95222474
 H                  0.37771684    0.25689113   -0.16676258
 H                  1.61939318   -0.94633530    0.06198374
 C                  2.70539448    0.68593445   -0.96698551
 O                 -0.23363600   -0.87964100    1.71136600
 S                 -1.16315500    0.01450800    2.58393100
 O                 -1.73005900   -0.78098300    3.66305500
 O                 -0.58297200    1.32266800    2.85932800
 C                 -2.59513600    0.33671000    1.39454000
 F                 -3.51977600    1.08487800    2.00485600
 F                 -2.15701900    0.98608900    0.31146500
 F                 -3.15180200   -0.81534000    1.01309900
 O                  3.55827602    1.20367645   -1.63372106

