%mem=30000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3oTs-ch3-ts_6311+Gd_new

-1 1
 C                  0.90884200    0.02185200    0.26808400
 H                  1.40657200   -0.41651800    1.11792000
 H                  0.98666000    1.09169000    0.16066600
 H                  0.93169200   -0.55184700   -0.64335400
 C                  3.44542600    0.06443700   -0.62861400
 H                  4.39679900    0.54401200   -0.34208300
 H                  3.59714400   -1.02557400   -0.57739000
 H                  3.25141800    0.32082900   -1.68267700
 O                 -0.73554700   -0.20297600    0.62356400
 S                 -1.26606400    0.39853700    1.97503800
 O                 -0.64469600   -0.29923700    3.11895800
 O                 -1.11938300    1.86829300    1.96710300
 C                 -2.99905500   -0.01643600    1.91343700
 F                 -3.69576745    0.84510190    2.68469844
 F                 -3.43642212    0.06572703    0.63889424
 F                 -3.17707680   -1.27432589    2.37007828

