%mem=30000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3nc5h5-oTs-ts_6311+Gd_new

0 1
 C                 -0.72277958   -0.12416390   -0.20629018
 H                 -1.20349258    0.32082610    0.66116782
 H                 -1.01426458    0.40989810   -1.10796718
 H                 -0.99984458   -1.16998990   -0.28738118
 N                  1.20889300    0.01271000    0.00492200
 C                  1.98731200   -1.08937000   -0.04216000
 C                  1.75111900    1.23779300    0.19063200
 C                  3.35895300   -0.98880400    0.10083500
 H                  1.48209100   -2.03225500   -0.19539500
 C                  3.11454700    1.39018400    0.33754000
 H                  1.05733500    2.06709500    0.21479100
 C                  3.93467500    0.26362800    0.29318000
 H                  3.95764300   -1.88913600    0.06037500
 H                  3.51997300    2.38253000    0.48486500
 H                  5.00741900    0.36249300    0.40791500
 O                 -3.00066349   -0.07139046   -0.25034221
 S                 -3.79262409    1.11982015    0.17996366
 O                 -3.55150046    2.31824537   -0.67885147
 O                 -3.61116368    1.42222212    1.63614226
 C                 -5.52823534    0.68143536   -0.03381756
 F                 -5.92622423   -0.09562971    0.99587886
 F                 -5.68243104    0.00647163   -1.19276003
 F                 -6.27570902    1.80519341   -0.06465489

