%mem=20000MB
%nprocshared=12
#p opt=(calcfc,ts,modredundant,noeigentest,loose,maxstep=2,maxcycles=250)
freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane) nosymm
empiricaldispersion=gd3

ch3hcooo-h2o ch2lc2

0 1
 C                 -1.22523300    0.36025500   -0.22333600
 H                 -0.74139400   -0.61692000   -0.11296500
 H                 -1.47927400    0.94640100    0.67071100
 H                 -1.29348400    0.83590200   -1.20685800
 O                  0.88665600    1.45103900   -0.15555000
 O                  2.10425100    0.83853900    0.34876300
 C                  2.09830600   -0.47106500    0.49459600
 H                  3.06105500   -0.77742600    0.93482000
 O                  1.20448400   -1.23847300    0.20651500
 O                 -3.11581100   -0.45468800   -0.39948000
 H                 -3.26649700   -0.90175200    0.45832300
 H                 -3.72924200    0.30727200   -0.38447000

B 1 10 F
B 5 1 F

