%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp 6-311+g(d) scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3hcooo-sime3-ts_6311+Gd_new

-1 1
 C	 0.766234000	 0.187182000	 0.468656000
 H	 0.618921000	-0.819850000	 0.112428000
 H	 0.507812000	 1.008821000	-0.183621000
 H	 0.741399000	 0.357446000	 1.532040000
 Si	-2.038383000	 0.048317000	 0.220379000
 C	-2.032782000	-1.323593000	-1.146326000
 H	-1.200984000	-1.187737000	-1.849561000
 H	-1.922908000	-2.327677000	-0.716654000
 H	-2.960909000	-1.322619000	-1.737814000
 C	-3.737609000	-0.302328000	 1.088387000
 H	-3.729716000	-1.254500000	 1.633389000
 H	-3.992914000	 0.477946000	 1.816173000
 H	-4.560841000	-0.350411000	 0.358756000
 C	-2.484579000	 1.605693000	-0.842032000
 H	-2.682402000	 2.484850000	-0.215681000
 H	-1.668537000	 1.879359000	-1.523223000
 H	-3.380050000	 1.438243000	-1.459940000
 O	 2.519374000	 0.343528000	 0.174200000
 O	 3.210735000	-0.693319000	 0.934335000
 C	 3.323096000	-1.826564000	 0.228159000
 H	 2.921545000	-1.760303000	-0.789934000
 O	 3.840296000	-2.809309000	 0.716529000



