%nprocshared=20
%mem=40GB
#p freq=noraman
b3lyp/genecp scrf=(smd,solvent=dichloromethane) nosymm
empiricaldispersion=gd3

test of the TS hcooo-AuPMeCH3-CH3

0 1
 Au                -0.39152500    1.30721500    1.13342800
 P                  1.70973800    0.97071100   -0.02262400
 C                  2.08870200    2.28395100   -1.23571100
 H                  2.10034600    3.25452400   -0.73561100
 H                  3.06178400    2.10646100   -1.70097000
 H                  1.32198000    2.29898800   -2.01256200
 C                  3.17194300    0.90605800    1.07387500
 H                  3.06148100    0.08318300    1.78336200
 H                  4.08354100    0.75687300    0.48938100
 H                  3.25203100    1.84049200    1.63329800
 C                  1.77920600   -0.57903100   -0.98918600
 H                  2.74629000   -0.67835600   -1.48891800
 H                  1.62692900   -1.43264700   -0.32547100
 H                  0.98790300   -0.57564600   -1.74176000
 C                 -1.52575500    1.69959500   -0.78562700
 H                 -2.51776400    1.90797700   -0.41903400
 H                 -0.92281000    2.53323200   -1.10919800
 H                 -1.34634000    0.73010500   -1.22428000
 C                 -2.16538800    1.58938300    2.20241600
 H                 -2.91175900    0.83280600    1.94095500
 H                 -1.93983600    1.50256900    3.27253200
 H                 -2.59306500    2.57927800    2.01664300
 O                 -2.52210700    2.06997800   -2.76200600
 C                 -1.78218300    1.19759100   -4.76801600
 O                 -1.43335100    1.89740700   -3.68799900
 O                 -0.98098400    0.91209900   -5.63486700
 H                 -2.84507600    0.92010000   -4.79208600

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
****

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


