%nprocshared=24
%mem=40GB
#p opt=(calcfc,ts,noeigentest,maxstep=10) freq=noraman b3lyp/genecp
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

test of the TS hcooo-Pdcomplex

0 1
 C                 -1.47759200    1.53502200   -0.75694600
 H                 -2.43565600    1.66651600   -0.27857300
 H                 -0.91511300    2.39526000   -1.07125600
 H                 -1.13178500    0.54499100   -0.99362600
 O                 -2.41006600    1.57968500   -2.52647400
 C                 -0.92641300    0.35450500   -3.79528700
 O                 -1.31287600    1.58775800   -3.47746600
 O                  0.01518500    0.14767000   -4.52967900
 H                 -1.54839400   -0.42699200   -3.33388000
 Pd                -0.28712900    1.45670800    1.32106100
 P                 -0.46105834   -0.87068648    1.34080820
 P                 -0.04053327    3.77498168    1.37893080
 C                  1.09838013   -1.82703561    1.15313066
 C                 -1.16972549   -1.57564980    2.88457194
 C                 -1.53956577   -1.62691830    0.05705463
 C                  1.66109018    4.43655842    1.16036978
 C                 -0.99716274    4.73782371    0.13751197
 C                 -0.56917916    4.56646997    2.95271241
 H                  1.79128189   -1.56090384    1.95416399
 H                  0.89914583   -2.90171972    1.19280576
 H                  1.56638214   -1.58430562    0.19672172
 H                 -1.23325623   -2.66555632    2.82057361
 H                 -0.54267303   -1.30190708    3.73563858
 H                 -2.17018133   -1.16919543    3.04794734
 H                 -1.57888292   -2.71364640    0.17457552
 H                 -2.55029197   -1.22173922    0.14344510
 H                 -1.15506831   -1.38689503   -0.93643745
 H                  2.05216979    4.13280662    0.18702831
 H                  1.66123133    5.52849866    1.22252531
 H                  2.31468890    4.03289862    1.93658046
 H                 -2.06175518    4.51830617    0.24541797
 H                 -0.83779345    5.81143528    0.27250431
 H                 -0.68649658    4.45255412   -0.86975926
 H                  0.02520191    4.17284100    3.77991145
 H                 -0.44243928    5.65163265    2.90337898
 H                 -1.62002591    4.33816567    3.14362989

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
****

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


