%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3nhc

0 1
 C                 -0.00000300    0.00005700   -0.66557000
 H                 -0.00200372    1.03650407   -1.00199900
 H                  0.89862643   -0.51654547   -1.00205095
 H                 -0.89661818   -0.52003357   -1.00204805
 N                 -0.00000092    0.00001756    0.80443000
 C                  1.13169121    0.00811445    1.61455873
 C                 -1.13154076   -0.00767847    1.61478595
 C                  0.71768526    0.00546580    2.95377310
 H                  2.13494586    0.01498118    1.19037018
 C                 -0.71715074   -0.00461246    2.95398357
 H                 -2.13476797   -0.01466028    1.19062537
 H                  1.36112176    0.01012943    3.82715736
 H                 -1.36033438   -0.00893603    3.82754639

