%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3f

0 1
 C                 -0.00000300    0.00005700   -0.66557000
 H                  0.00000600    1.03650600   -1.00199900
 H                  0.89762300   -0.51828700   -1.00205100
 H                 -0.89762500   -0.51829400   -1.00204800
 F                 -0.00000100    0.00001900    0.75080800

