%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3c5h5n

1 1 
 C                 -0.00000300    0.00005700   -0.66557000
 H                 -0.00401343    1.03649824   -1.00199900
 H                  0.89962648   -0.51480200   -1.00205090
 H                 -0.89560799   -0.52177118   -1.00204810
 N                 -0.00000092    0.00001756    0.80443000
 C                 -1.14996174   -0.00502020    1.50623259
 C                  1.15012901    0.00501839    1.50633160
 C                 -1.20122080   -0.00530221    2.91217645
 H                 -2.07753808   -0.00907936    0.90649067
 C                  1.20173893    0.00534343    2.91234762
 H                  2.07765798    0.00916081    0.90637923
 C                  0.00026855    0.00011599    3.62311639
 H                 -2.16769602   -0.00943524    3.43203965
 H                  2.16836365    0.00960334    3.43194808
 H                 -0.00000300   -0.00087417    4.72238019

