%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3nch

1 1 
 C                  0.00454600    0.00071100    0.80903899
 N                  1.15577400    0.00071100    0.80903900
 H                 -1.06955900    0.00071100    0.80903898
 C                  2.62577400    0.00070471    0.80903900
 H                  2.98244253    0.51124146   -0.06104133
 H                  2.98244248    0.49894549    1.68621841
 H                  2.98243654   -1.00807745    0.80193992

