%mem=16000MB
%nprocshared=12
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

pcl3

0 1 
 P                 -0.00001200   -0.00273300    1.11091500
 Cl                -1.61429400    0.93593900    1.83063400
 Cl                 1.61426500    0.93593600    1.83065100
 Cl                -0.00001700   -1.86924300    1.83581700

