%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3

-1 1 
 C                 -0.00476300   -0.00269000   -0.66752000
 H                  0.02692400    1.03474600   -1.01499300
 H                  0.90956100   -0.49399900   -1.01487000
 H                  0.02691500    0.01565600    0.42643000

