%nprocshared=24
%mem=120GB
#p opt=(calcfc,ts,modredundant,noeigentest,maxstep=15) freq=noraman
b3lyp/genecp scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ts test Pdcomplex ch3c6h5

0 1
 C                  1.10528600    1.34579300    4.13576000
 H                  1.31826400    0.29317100    4.24929100
 H                  1.96197200    1.99813900    4.04562500
 H                  0.27004100    1.72823300    4.70745000
 C                  2.14824100    1.32069600    6.45326200
 C                  1.95518100    0.34710200    7.44535700
 C                  3.13131100    2.28874100    6.70735600
 C                  2.69841700    0.33550600    8.63606000
 H                  1.20761200   -0.43627100    7.30737900
 C                  3.88522000    2.29736100    7.89086300
 H                  3.33200900    3.06998700    5.97131800
 C                  3.66890800    1.31539700    8.86150300
 H                  2.52260500   -0.43451100    9.38476700
 H                  4.63898500    3.06486800    8.05584200
 H                  4.24914500    1.31310800    9.78006400
 Pd                -0.01376633    1.47717268    1.57246890
 P                 -0.84787333   -0.70850232    1.59732190
 P                  0.82784767    3.65289168    1.41654790
 C                 -1.63437233   -1.31974732    0.05191990
 C                  0.39536067   -2.01908232    1.94171090
 C                 -2.12976433   -1.06664332    2.86550490
 C                  0.60661067    4.54990368   -0.17233910
 C                  0.16928267    4.85136168    2.64524490
 C                  2.63933367    3.78712068    1.70427090
 H                 -0.91406933   -1.27702632   -0.76779810
 H                 -1.97763733   -2.35087332    0.17535390
 H                 -2.48654233   -0.68642232   -0.20371210
 H                 -0.07631533   -3.00563932    1.95228590
 H                  1.17131767   -2.00050732    1.17353990
 H                  0.86474667   -1.83929132    2.91097190
 H                 -2.43554533   -2.11580032    2.82295490
 H                 -1.72959433   -0.85059332    3.85879690
 H                 -3.00204233   -0.43119432    2.69880290
 H                 -0.45818833    4.64486468   -0.39547410
 H                  1.05258367    5.54705468   -0.11786310
 H                  1.08048167    3.98841868   -0.98029610
 H                  0.35457267    4.47738568    3.65468590
 H                  0.64996367    5.82697868    2.53098290
 H                 -0.90851933    4.96379868    2.51070590
 H                  3.17948567    3.20194668    0.95734790
 H                  2.96362667    4.82986468    1.64920990
 H                  2.87598467    3.39027168    2.69492390

B 1 15 B
B 1 5 B

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
****

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


