%nprocshared=24
%mem=120GB
#p opt=(calcfc,ts,noeigentest,maxstep=15) freq=noraman
b3lyp/genecp scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ts test Pdcomplex ch3c6h5

0 1
 C                  1.10198300    1.37548800    4.26738900
 H                  1.34231600    0.32878500    4.39443100
 H                  1.95049700    2.03909600    4.17657100
 H                  0.29104600    1.74119500    4.88362500
 C                  2.24175500    1.34970500    6.59689000
 C                  2.08191500    0.38288500    7.60121300
 C                  3.24145200    2.31158700    6.80452700
 C                  2.87283100    0.37285100    8.76089900
 H                  1.32430500   -0.39615500    7.49860500
 C                  4.04259700    2.32159900    7.95655900
 H                  3.41835200    3.08689600    6.05653100
 C                  3.85803900    1.34721200    8.94099100
 H                  2.72207500   -0.39151800    9.52081100
 H                  4.80788200    3.08446300    8.08635700
 H                  4.47425600    1.34636800    9.83543100
 Rh                 0.23088300    1.43759900    2.27396700
 N                  1.80628300    2.48216000    1.55320600
 N                 -0.33824500    3.29359100    2.66329000
 N                 -1.33149700    0.46709300    3.01411400
 N                  0.75738700   -0.48006000    1.90500100
 C                  1.73652300    3.76639400    1.73114400
 C                  2.92418500    1.74651200    0.95285200
 C                  0.50147900    4.25409300    2.41594100
 O                 -1.49015900    3.54902800    3.34902700
 C                 -1.28131400   -0.83089200    3.04787500
 O                 -2.33490200    1.13333700    3.65552100
 C                 -0.07267300   -1.37116700    2.35495700
 C                  2.03425800   -0.73632600    1.23118100
 C                  2.77414600    4.75862800    1.31576100
 H                  2.73337100    1.67356200   -0.12341000
 H                  3.86107600    2.28955100    1.08745300
 C                  3.09609900    0.33517900    1.54712600
 C                  0.24263600    5.68897600    2.75221500
 B                 -2.58584400    2.53337200    3.16073700
 C                 -2.33185800   -1.68520400    3.68494100
 C                  0.08830800   -2.85205300    2.23218100
 H                  2.43483800   -1.71055600    1.51565500
 H                  1.84107200   -0.75825000    0.15311700
 H                  3.30362400    5.13879500    2.19582100
 H                  3.50196500    4.33172200    0.62963000
 H                  2.30349800    5.61585100    0.82926300
 H                  4.03772400   -0.04714800    1.14138900
 H                  3.23491800    0.40666500    2.62932200
 H                  1.19225000    6.19889300    2.92263600
 H                 -0.31966700    5.73279300    3.68698100
 C                 -0.54499200    6.39825800    1.63674600
 F                 -2.93803800    2.48389000    1.79968600
 F                 -3.63263100    3.00051000    3.95508100
 H                 -1.88220400   -2.61931300    4.02553400
 H                 -2.71192300   -1.16918200    4.56893300
 C                 -3.48996100   -1.97904900    2.71550500
 H                  0.32775100   -3.28658300    3.20829300
 H                 -0.84785300   -3.30639900    1.89922400
 H                  0.87140300   -3.12498000    1.52879600
 H                 -0.71885300    7.44305000    1.90582200
 H                  0.00261400    6.37685200    0.69124600
 H                 -1.51452500    5.91939600    1.48003300
 H                 -3.13687400   -2.50593100    1.82556600
 H                 -4.24025100   -2.60427400    3.20580200
 H                 -3.97319100   -1.05327600    2.39417600

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
****

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -Br -I -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd



