%mem=30000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3c6h5-s-ts_6311+Gd1_new

-2 1
 C                 -0.72629000   -0.25994700    0.21552500
 H                 -0.90546300   -1.27243700    0.52195600
 H                 -0.67822000    0.52353000    0.94483900
 H                 -0.59268100   -0.02681700   -0.82481800
 S                 -3.16156000    0.11041100   -0.08061100
 C                  1.95381268   -1.85411334    0.20750439
 C                  3.34897268   -1.85411334    0.20750439
 C                  4.04651068   -0.64636234    0.20750439
 C                  3.34885668    0.56214666    0.20630539
 C                  1.95403168    0.56206866    0.20582639
 C                  1.25643068   -0.64613734    0.20682239
 H                  1.40405368   -2.80643034    0.20795439
 H                  3.89848068   -2.80662634    0.20881939
 H                  5.14619068   -0.64628234    0.20813839
 H                  3.89905668    1.51428966    0.20624639
 H                  1.40390968    1.51434966    0.20487339

