%mem=30000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3c6h5-sime3-ts_6311+Gd_new

-1 1
 C                  0.73350500   -0.14430900   -0.29334400
 H                  0.71879762   -1.21645234   -0.35400491
 H                  0.44268536    0.44985307   -1.14257122
 H                  0.85570608    0.32570021    0.66752664
 Si                -1.86669300   -0.12757400   -0.01292500
 C                 -2.39514400   -1.09557700   -1.59373100
 H                 -1.78090500   -0.81688300   -2.45898500
 H                 -2.28669200   -2.17927600   -1.46186900
 H                 -3.44450100   -0.90332100   -1.86247200
 C                 -3.22267700   -0.64673600    1.26314700
 H                 -3.15062400   -1.70906500    1.52536700
 H                 -3.14248900   -0.07951600    2.19818000
 H                 -4.23379800   -0.47648500    0.86228500
 C                 -2.37899100    1.67855800   -0.45077400
 H                 -2.26863100    2.35340600    0.40696500
 H                 -1.76170300    2.08790800   -1.26012400
 H                 -3.42732300    1.73751200   -0.77925900
 C                  2.59638340    0.09420763   -0.58108324
 C                  3.46607349   -0.98894080   -0.45468401
 C                  3.09428385    1.35280879   -0.91935555
 C                  4.83391154   -0.81362246   -0.66623538
 H                  3.07367691   -1.98103843   -0.18839460
 C                  4.46184033    1.52826181   -1.13040658
 H                  2.40828254    2.20655224   -1.01934829
 C                  5.33194264    0.44474010   -1.00344514
 H                  5.51939106   -1.66759149   -0.56575405
 H                  4.85474410    2.52032878   -1.39635037
 H                  6.41015280    0.58313934   -1.16959273

