%mem=30000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=6) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3c6h5-co-ts_6311+Gd_new

0 1 
 C                  1.31692400   -0.21346900   -0.04933100
 H                  1.56155100   -1.16402100    0.38921700
 H                  1.15543800    0.64239300    0.57926400
 H                  1.25602300   -0.10251900   -1.11627100
 C                  3.41478094    0.25025410   -0.12968728
 C                 -0.77815200   -0.72587100    0.04622300
 C                 -1.77047900   -0.02739200   -0.66097000
 C                 -1.22752500   -1.79096700    0.84255500
 C                 -3.13030300   -0.36145600   -0.58548400
 H                 -1.48759600    0.81249600   -1.30155900
 C                 -2.58040700   -2.14762800    0.93810000
 H                 -0.50428200   -2.37643000    1.41747300
 C                 -3.54007800   -1.42878900    0.21941900
 H                 -3.86972300    0.20382700   -1.15013800
 H                 -2.88870700   -2.98086300    1.56720500
 H                 -4.59080300   -1.69636600    0.28493700
 O                  4.43496958    0.64549985   -0.24368700

