%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3pcl3-nh3-ts_6311+Gd1sp_new

1 1
 C                  1.88062800    0.00895000    0.02737200
 H                  1.98080800    0.06620200    1.10279700
 H                  1.98190700   -0.95102700   -0.46108200
 H                  1.98260700    0.91206900   -0.55979700
 P                 -0.25438600    0.00337000    0.00858000
 Cl                -1.09865900   -1.57946000    1.00202100
 Cl                -1.04253700   -0.09629300   -1.88143300
 Cl                -1.12390200    1.66225300    0.84293700
 N                  4.10436800    0.00959300    0.02510800
 H                  4.45447600    0.90259200    0.35810700
 H                  4.44915700   -0.14580400   -0.91709100
 H                  4.45915200   -0.72594800    0.62845100

