%mem=3000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-nh2-ts_6311+Gd

1 1
 C                 -0.08643300    0.00628400   -0.02563100
 H                  0.13205300   -0.15503100   -1.06727100
 H                  0.07918100    0.97997700    0.40321000
 H                 -0.18088300   -0.84653400    0.62416200
 N                  2.10239500   -0.32621200    0.24707200
 H                  2.61120000    0.34982100   -0.28593400
 H                  2.33584400   -0.23195000    1.21486100
 H                 -2.33149853    0.54494932   -1.24198692
 H                 -2.62744553   -0.58348368   -0.09930492
 H                 -2.47947253    0.98698632    0.32306108
 H                  2.34138300   -1.24556400   -0.06545900
 P                 -2.15165853    0.27370332   -0.29642692

