%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-s-ts_6311+Gd1_new

-1 1
 C                  0.00000000    0.55434900    0.00000000
 H                 -1.05596700    0.76158300    0.00000000
 H                  0.53377300    0.72413700    0.91831800
 H                  0.53377300    0.72413700   -0.91831800
 S                  0.10726500    3.44187200    0.00000000
 N                  0.00886888   -1.58210259   -0.01132293
 H                 -0.92160609   -1.94380023   -0.06955651
 H                  0.33664223   -1.65537566    0.93058773
 H                  0.60895799   -2.10709274   -0.61487772

