%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-ch3-ts_6311+Gd1_new

0 1 
 C                  0.95644400    0.00016400    0.13326000
 H                  1.13993300   -0.91459100    0.67334300
 H                  1.13961600    0.91344400    0.67594800
 H                  1.24510300    0.00169700   -0.90501900
 C                  3.71453800   -0.00002700   -0.01026900
 H                  4.54455700   -0.00055300    0.71506600
 H                  3.81823800   -0.89049500   -0.64796100
 H                  3.81924200    0.89044400   -0.64779900
 N                 -1.10977892    0.02176615    0.01014947
 H                 -1.52630934    0.92983006    0.05399405
 H                 -1.54043892   -0.57552747    0.68673818
 H                 -1.24093694   -0.36132920   -0.90420032

