%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nch-nh3-ts_6311+Gd2_new

1 1
 C                 -0.97543300   -0.01320800    0.00199500
 H                 -0.90332300   -0.71393500    0.81450900
 H                 -0.90511900   -0.36626600   -1.01144700
 H                 -0.90364600    1.04094900    0.20315900
 N                 -2.87010100   -0.01061700    0.00401700
 C                 -4.01415900    0.01367200   -0.00441000
 H                 -5.08988000    0.03670800   -0.01245200
 N                  1.50456366   -0.01221804   -0.00195067
 H                  1.83788556   -0.95503113   -0.00195067
 H                  1.83790277    0.45918213    0.81454606
 H                  1.83790277    0.45918213   -0.81844740

