%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nc5h5-nh3-ts_6311+Gd_new

1 1 
 C                 -0.71662300    0.00889000   -0.01724300
 H                 -0.67845100   -0.16985800    1.04169400
 H                 -0.70267600    1.01647000   -0.39223400
 H                 -0.69621200   -0.82095300   -0.70030800
 N                  1.39696700    0.01517200   -0.04262700
 C                  2.05617900   -1.14867500   -0.02351000
 C                  2.08235900    1.16365400   -0.02284700
 C                  3.44492500   -1.20967200    0.01381800
 H                  1.44793800   -2.04715700   -0.03810800
 C                  3.47241600    1.19253800    0.01475000
 H                  1.49547500    2.07616400   -0.03720500
 C                  4.16516800   -0.01654900    0.03313800
 H                  3.94390500   -2.17128900    0.02745200
 H                  3.99329500    2.14245900    0.02928300
 H                  5.24900900   -0.02896400    0.06265000
 N                 -3.02659691    0.01908744   -0.01317306
 H                 -3.43107155    0.93362706   -0.00898526
 H                 -3.24819658   -0.44732292    0.84318841
 H                 -3.39350203   -0.50414387   -0.78233470

